碳化硼涂覆的碳纤维的抗热氧化性研究

用自己合成的裂解能得到碳化硼的聚碳硼烷,对碳纤维进行涂层,并详细测试了涂层碳纤维的抗热氧化性能。     

湿热环境中油罐防腐设计

湿热环境中油罐的腐蚀主要体现为电化学腐蚀的特征，适宜的防腐措施对提高油罐的建设质量，减缓油罐的腐蚀速度，延长油罐的使用寿命，减小维护费用等具有积极的意义。从分析湿热环境中油罐腐蚀规律出发，介绍了油罐内外壁防腐涂层的选用原则，对3000m^3地面立式油罐的牺牲阳极电法保护进行了设计计算，提出了施工方法，对湿热环境中油罐防腐具有指导意义。     

Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.     

Thomas Firth and Sons – Steelmakers to the Arms Industries. Part 2: Heavy Armaments

Firth’s were the first of the Sheffield steel makers to enter the field armaments. Their involvement with Colt has been outlined in an article in the journal of the Colt Collectors Association in America and their activities as steelmakers to the small-arms industries has been covered in a previous issue of this Journal. This article gives a brief overview of their involvement as manufacturers in the field of heavy armaments, being the first to make all-steel guns and their evolving role in the use of steel for ordnance, culminating in the displacement of wrought iron by the adoption of steel for ordnance manufacture by the Royal Gun Factory in the 1880s. It also highlights their development of stainless steel in this context.     

Damage analysis of POZD coated square reinforced concrete slab under contact blast

High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone (POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification, numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases, and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.     

一种新型CVD铁涂层吸波纤维

利用Fe(CO)5受热分解,以CVD方法在SiC纤维表面涂覆单质铁的涂层。研究表明,涂层的引入对SiC纤维力学性能基本没有损伤;纤维依靠涂层导电,其电阻率显著降低;改变工艺条件,可以在较大范围内调节涂层纤维的介电常数,同时也引入了磁损耗机制;采用较低的沉积温度和较高的载气流速,可以提高介电常数和磁导率,同时有好的频散效应。     

一种拦截机动目标的最优制导律设计

引入伪控制变量的概念,建立了线性化的描述导弹与目标相对运动的状态方程.应用线性二次型最优控制理论和改进剩余时间的计算方法,提出了一种拦截高机动目标的最优制导律.通过与比例导引律在平面拦截过程中的仿真结果对比分析,表明所提出的最优制导律在拦截机动目标时更为有效.     

基于微动调制的SAR新型复合有源干扰方法

在静态虚假目标的基础上,利用有源运动调制干扰原理,提出了一种基于微动调制的SAR新型复合有源干扰方法。建立了基于微动调制的复合有源干扰信号模型,详细分析了该干扰信号对SAR的干扰效果,确定了各调制系数,最后进行了基于实测数据的仿真实验。结果表明,该方法具有距离向相干处理和方位向部分相干处理的特点,可对SAR在方位向上实现多个匀(加)速虚假运动目标的欺骗干扰效果。     

两栖车辆用牺牲阳极材料研究进展

结合两栖车辆的发展和两栖车辆牺牲阳极阴极保护性能指标要求,介绍了两栖车辆用牺牲阳极材料研究进展,分析了主要合金元素作用机理。根据牺牲阳极耐干湿交替性能要求和实车试验结果,采用极化时间、车体保护电位、活化性能等技术指标,评价了五元和六元牺牲阳极对两栖车辆阴极保护效果。展望了两栖车辆牺牲阳极阴极保护研究的下一步工作方向和重点。     

PIP工艺制备的C/SiC复合材料的氧化行为

PIP工艺制备的C/SiC复合材料中SiC基体富碳,因此增强体和基体均容易氧化。碳纤维和无涂层保护C/SiC复合材料试样在400~1300℃的氧化速率随温度升高而加快,低温为反应控制,高温为扩散控制。CVD-SiC涂层保护C/SiC复合材料和由CVD-SiC层、自愈合层、CVD-SiC层三层涂层保护C/SiC复合材料在400~1300℃的氧化先随温度升高而加快,然后减慢。三层涂层在800~1300℃有非常好的保护效果。扫描电镜照片显示自愈合层的玻璃态物质进入涂层裂纹中,填充裂纹且阻挡氧的通过,从而有良好的抗氧化保护效果。